تفاصيل الوثيقة

نوع الوثيقة : مقال في مجلة دورية 
عنوان الوثيقة :
A Novel Poly(p-phenylene) Containing Alternating Poly(perfluorooctylethyl acrylate-co-methyl methacrylate) and Polystyrene Grafts by Combination of Atom Transfer Radical Polymerization and Suzuki Coupling Processes
A Novel Poly(p-phenylene) Containing Alternating Poly(perfluorooctylethyl acrylate-co-methyl methacrylate) and Polystyrene Grafts by Combination of Atom Transfer Radical Polymerization and Suzuki Coupling Processes
 
لغة الوثيقة : الانجليزية 
المستخلص : A poly(p-phenylene) (PP), carrying perfectly alternating, well-defined poly(perfluorooctylethyl acrylate-co-methyl methacrylate) [P(FEA-co-MMA)] and polystyrene (PS) side chain grafts, was synthesized by the combination of atom transfer radical polymerization (ATRP) and Suzuki cross-coupling processes. First, dibromobenzene and diboronic ester functional macromonomers of P(FEA-co-MMA) and PS, respectively, were prepared by ATRP. In the second step, PP with lateral alternating P(FEA-co-MMA) and PS chains was synthesized by a Suzuki coupling reaction in the presence of Pd(PPh3)(4) catalyst. The wetting behavior of the polymers was studied by measurements of the static contact angle theta of thin films (200-400 nm thickness) using water and n-hexadecane as wetting liquids. The obtained fluorinated PP showed high static contact angles with both interrogating liquids, exhibiting simultaneously hydrophobic (theta(w) = 111 degrees) and lipophobic (theta(h) = 67 degrees) properties. 
ردمد : 0887-624X 
اسم الدورية : JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 
المجلد : 50 
العدد : 23 
سنة النشر : 1433 هـ
2012 م 
نوع المقالة : مقالة علمية 
تاريخ الاضافة على الموقع : Tuesday, July 11, 2017 

الباحثون

اسم الباحث (عربي)اسم الباحث (انجليزي)نوع الباحثالمرتبة العلميةالبريد الالكتروني
y DurmazDurmaz, y باحث  
e SahkulubeySahkulubey, e باحث  
y YagciYagci, y باحث  
E MartinelliMartinelli, E باحث  
G GalliGalli, G باحث  

الملفات

اسم الملفالنوعالوصف
 42066.pdf pdf 

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